A recent study indicates that mechanical fatigue of the lithium metal anode, rather than just current density, is the primary factor leading to dendrite-induced short circuits and the failure of Solid-State Batteries (SSBs)
What are Solid-State Batteries (SSBs)?
(SSB) is a sophisticated kind of battery that utilizes a solid electrolyte rather than the liquid or gel-like electrolyte present in traditional lithium-ion batteries.
Functioning Principle:
Charging Phase: Lithium ions transfer from the cathode to the anode via the solid electrolyte, accumulating energy.
Discharge Phase: Lithium ions move from the anode to the cathode, producing an electric current that powers devices or vehicles.
Obstacles in Solid-State Batteries (SSBs)
Lithium Dendrite Development: Dendrites are slender, hair-like metallic structures of lithium that form on the anode during multiple charging cycles.
These structures develop when lithium ions (Li⁺) deposit unevenly during the charging process. These dendrites are capable of:
Penetrate the dense electrolyte,
Arrive at the cathode, and
Create a short circuit, making the battery hazardous and unserviceable.
Dendrites can develop even at low current densities because of the cyclic mechanical fatigue of the lithium metal anode.
The Coffin-Manson principle of material fatigue, a recognized concept in the field of materials science, was deemed relevant to the deterioration of lithium metal.
Uses of Solid-State Batteries
Electric Vehicles (EVs): Toyota and BMW are working on SSB-driven EVs that offer enhanced range and fast charging.
Consumer Electronics: Firms such as Apple and Samsung are putting money into SSBs to create safer and more durable smartphones and laptops.
Grid Storage: Tesla along with other major energy companies are exploring SSBs for solutions in renewable energy storage.
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